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排序方式: 共有258条查询结果,搜索用时 15 毫秒
1.
通过高温煅烧ZnSn(OH)6前驱体制备了双壳中空立方体结构的ZnSnO3(ZSO),进而采用水热法将CdIn2S4(CIS)纳米晶包裹在ZSO表面,成功制备了CdIn2S4/ZnSnO3(CIS/ZSO)异质催化剂。活性产氢实验结果表明,CIS、ZSO物质的量之比为12%时制备的12% CIS/ZSO具有优异的光催化产氢性能,在3 h内产氢量为1 676.48 μmol·g-1,分别是ZSO和CIS的12倍和8倍。ZSO光催化析氢反应活性的增强归因于CIS/ZSO异质结构的成功构建,异质界面的形成显著提高了光生电子/空穴对的分离效率,降低了其复合率。通过对电荷转移路径的分析,提出了可能的反应机理。 相似文献
2.
利用中学物理实验中半偏法测量电表内阻的思想,通过给电表并联和串联电阻,调节串并联电阻的阻值使电表指针达到满偏和半偏的方法测量电表内阻,拓展了测量电表内阻的方法。 相似文献
3.
BiFeO3 perovskite with 2D laminated cylinder-like structure was prepared via a facile one-pot hydrothermal method, whose morphologies and optical properties was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersion spectrum (EDS), and UV-Visible diffuse reflectance spectroscopy (UV-Vis DRS). The photocatalytic properties of the as-prepared BiFeO3 composites were evaluated according to degrading Rhodamine B (RhB) and desulfurization under visible light irradiation, with excellent photocatalytic degradation and desulfurization activity found. Moreover, the mechanism study of active free radicals in photocatalytic activity indicates that the h+ radical in holes was mainly responsible for synergistic catalytic efficacy in photocatalytic degradation. 相似文献
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Xing Hui GAO Hai Yun ZHOU . College of Mathematics Computer Science Yan’an University Shaanxi P. R. China . Department of Basic Courses Shijiazhuang Mechanical Engineering College Hebei 《数学研究与评论》2011,31(5)
The purpose of this article is to propose a shrinking projection method and prove a strong convergence theorem for a family of quasi-φ-strict asymptotically pseudo-contractions. Its results hold in reflexive, strictly convex, smooth Banach spaces with the property (K). The results of this paper improve and extend the results of Matsushita and Takahashi, Marino and Xu, Zhou and Gao and others. 相似文献
7.
Y. Q. Zhang J. X. Wang Y. L. Shang Y. L. Song L. Jiang 《Applied Physics A: Materials Science & Processing》2011,102(3):531-536
The acid-base vapors/light double responsive dye-infiltrated SiO2 inverse opal photonic crystals (PCs) were fabricated by sacrificial template method and a subsequent infiltration of spiropyran
derivative dye molecules. The fluorescence of ring-open dye molecules infiltrated in PCs can be switched on/off based on different
fluorescence properties of spiropyran dye under stimuli of acid-base vapors or light, when PCs with suitable stopband were
selected. The fluorescence switch behavior based on PCs has potential applications in data storage, color displays, chemical
and biological sensors. 相似文献
8.
Long Tang Liang Bai Yaping Duan Wei Xia Wenwen Dong Dongsheng Li 《无机化学与普通化学杂志》2014,640(11):2268-2273
Three ZnII and CdII complexes with Y‐shaped dicarboxylate ligands, namely [Zn(L1)(2,2′‐bpy)2(H2O)] · 2H2O ( 1 ), [Zn(L1)(bpp)(H2O)] ( 2 ), and [Cd(L1)(H2O)] · H2O ( 3 ) [H2L1 = N‐phenyliminodiacetic acid, 2,2′‐bpy = 2,2′‐bipyridine, bpp = 1,3‐bis(4‐pyridyl)propane] were synthesized and characterized by elemental analysis, IR spectroscopy single‐crystal X‐ray diffraction, and thermogravimetric analyses. Compound 1 shows an hydrogen‐bonded 2D network, whereas compound 2 is an infinite 1D wavy chain structure, though O–H ··· O hydrogen‐bonded to form a 2D network. Compound 3 displays a 2D uninodal 3‐connected Shubnikov plane net with the point symbol of (4.82). Moreover, the solid‐state such as thermal stabilities and fluorescence properties of 1 – 3 were also investigated. 相似文献
9.
以3,3′,5,5′-(1,3-苯基)-联苯四羧酸(H4btb)与1,10-菲咯啉(phen)为配体,分别与硝酸镉和硝酸锌在水热条件下反应合成2个一维[Cd(H2btb)(phen)]n(1)和二维{[Zn2(btb)(phen)]·1.5H2O}n(2)配位聚合物,并对其进行了元素分析、红外光谱、热重分析和X-射线单晶衍射测定。配合物1属于单斜晶系,空间群为C2/c,晶胞参数:a=2.82845(13)nm,b=1.08554(5)nm,c=1.81768(8)nm,β=96.4850(10)°,V=5.5453(4)nm3,Z=8,Dc=1.670Mg·m-3,F(000)=2800,R1=0.0339,wR2=0.0718[I2σ(I)],配体H4btb的2个羧基分别采取μ1-η1∶η1、μ2-η2∶η1配位模式连接镉原子形成一维带状结构。化合物2也属于单斜晶系,空间群为P21/c,晶胞参数:a=1.7471(3)nm,b=1.2511(2)nm,c=2.1870(3)nm,β=120.911(11)°,V=4.1014(11)nm3,Z=4,Dc=1.491Mg·m-3,F(000)=1876,R1=0.0673,wR2=0.1749[I2σ(I)],全部去质子的H4btb配体的4个羧基分别采取μ1-η1∶η0、μ1-η1∶η1、μ2-η1∶η1配位模式连接锌原子形成一维链,链间通过μ2-η1∶η1桥连羧基扩展为(3,5)-连接的二维(42·67·8)(42·6)网状结构。同时研究了2个配合物的荧光性质。 相似文献
10.
《Journal of Analytical and Applied Pyrolysis》2009,84(2):205-212
Maize stalk was fast pyrolysed at temperatures between 420 °C and 580 °C in a fluidized-bed, and the main product of pyrolysis oil was obtained. The experimental results showed that the highest pyrolysis oil yield of 66 wt.% was obtained at 500 °C for maize stalk. Chemical composition of the pyrolysis oil acquired was analyzed by GC–MS and its heat value, stability, miscibility and corrosion characteristics were determined. These results showed that the pyrolysis oil could be directly used as a fuel oil for combustion in a boiler or a furnace without any upgrading. Alternatively, the fuel could be refined to be used by vehicles. 相似文献